Cut the red, green, yellow, and poblano peppers in half, remove seeds and stem then place face down on baking sheet. Skin side should be facing up.
Set oven to low broil, place peppers in the oven.
Dice onion and garlic. Add olive oil to a large pot, and place over medium-high heat, add in onions and garlic. Sautee until tender, remove from heat.
Once peppers start to become charred on the top, about 10-12 minutes, remove pan from oven and dice up the peppers. Add diced peppers to onions, place back over medium-high heat, cook stirring the onions and peppers together. Pour in drained and rinsed black and dark kidney beans. Gently stir.
Pour in tomato sauce, diced tomatoes and enchilada sauce. Stir in chili powder until chili is well combined. Bring a boil, then reduce heat to low, cover and simmer 30-45 minutes.
Meanwhile prepare quinoa according to package directions. One cup uncooked quinoa to 2 cups of water, bring to a boil, then cover and reduce heat to low and simmer for 15 minutes.
Once chili has cooked for 30 minutes, add in cooked quinoa. Stir and cook for another 10-15 minutes. Then it is ready to serve. You can keep this simmering uncovered over low heat for up to an hour.
Serve with cheese, sour cream, and chopped cilantro.